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ASTM F2625-10

Historical Revision

Standard Test Method for Measurement of Enthalpy of Fusion, Percent Crystallinity, and Melting Point of Ultra-High Molecular Weight Polyethylene by Means of Differential Scanning Calorimetry

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1.1 This test method discusses the measurement of the heat of fusion and the melting point of ultra-high-molecular weight polyethylene (UHMWPE), and the subsequent calculation of the percentage of crystallinity.

1.2 This test method can be used for UHMWPE in powder form, consolidated form, finished product, or a used product. It can also be used for irradiated or chemically-crosslinked UHMWPE.

1.3 This test method does not suggest a desired range of crystallinity or melting points for specific applications.

1.4 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.

1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.


The crystallinity of UHMWPE will influence its mechanical properties, such as creep and stiffness. The reported crystallinity will depend on the integration range used to determine the heat of fusion, and the theoretical heat of fusion of 100 % crystalline polyethylene used to calculate the percent crystallinity in an unknown specimen. Differential scanning calorimetry is an effective means of accurately measuring both heat of fusion and melting temperature.

This test method is useful for both process control and research.

SDO ASTM: ASTM International
Document Number F2625
Publication Date Dec. 1, 2010
Language en - English
Page Count 4
Revision Level 10
Supercedes
Committee F04.15
Publish Date Document Id Type View
March 15, 2024 F2625-24 Revision
Dec. 1, 2010 F2625-10 Revision
Feb. 1, 2007 F2625-07 Revision
April 1, 2016 F2625-10R16 Reaffirmation