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ASTM E538-98(2003)e1

Historical Reaffirmation

Standard Test Methods for Mercury in Caustic Soda (Sodium Hydroxide) and Caustic Potash (Potassium Hydroxide) (Withdrawn 2023)

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1.1 These test methods cover the routine determination of mercury in caustic soda and caustic potash liquors and anhydrous caustic soda in the solid, flake, ground, and bead form by the flameless atomic absorption method.

1.2 Two test methods are described as follows: Test Method A employs a direct analysis of the sample using an alkaline reducing agent with a lower limit of detection of 0.1 ppb (ng/g). Test Method A was developed using caustic soda and caustic potash. Test Method B requires a preliminary neutralization of the sample followed by a permanganate oxidation before it can be analyzed by an acidic reducing agent with a lower limit of detection of this test method of 0.01 ppm (g/g). Test Method B was developed using caustic soda.

1.3 The values stated in SI units are to be regarded as the standard.

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific hazards statements are given in Section 7 and 17.

1.5 Review the current material safety data sheets (MSDS) for detailed information concerning toxicity, first-aid procedures, and safety precautions.


Mercury is a toxic material and is also deleterious if present in caustic soda and caustic potash used in certain manufacturing processes. It must therefore be controlled as a possible pollutant. These test methods provide a procedure for measuring mercury in liquid and solid caustic soda and caustic potash.

SDO ASTM: ASTM International
Document Number E538
Publication Date April 10, 2003
Language en - English
Page Count 6
Revision Level 98(2003)e1
Supercedes
Committee E15.01
Publish Date Document Id Type View
July 1, 2017 E0538-17A Revision
April 15, 2017 E0538-17 Revision
Sept. 10, 1998 E0538-98 Revision
Dec. 15, 2008 E0538-98R08 Reaffirmation
April 10, 2003 E0538-98R03E01 Reaffirmation