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ASTM E2602-09

Historical Revision

Standard Test Methods for Assignment of the Glass Transition Temperature by Modulated Temperature Differential Scanning Calorimetry

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1.1 This test method describes the assignment of the glass transition temperature of materials using modulated temperature differential scanning calorimetry (MTDSC) over the temperature range from 120 to + 600 °C. The temperature range may be extended depending upon the instrumentation used.

1.2 SI units are the standard.

1.3 There are no ISO equivalents to this standard.

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.


Materials undergo an increase in molecular mobility at the glass transition seen as a sigmoidal step increase in the heat capacity. This mobility increase may lead to kinetic events such as enthalpic recovery, chemical reaction or crystallization at temperatures near the glass transition. The heat flow associated with the kinetic events may interfere with the determination of the glass transition.

The glass transition is observed in differential scanning calorimetry as a sigmoidal or step change in specific heat capacity.

MTDSC provides a test method for the separation of the heat flow due to heat capacity and that associated with kinetic events making it possible to determine the glass transition in the presence of interfering kinetic event.

This test method is useful in research and development, quality assurance and control and specification acceptance.

Other methods for assigning the glass transition temperature include differential scanning calorimetry (Test Method E 1356), thermomechanical analysis (Test Method E 1545) and dynamic mechanical analysis (Test Method E 1640)

SDO ASTM: ASTM International
Document Number E2602
Publication Date April 15, 2009
Language en - English
Page Count 4
Revision Level 09
Supercedes
Committee E37.01
Publish Date Document Id Type View
June 15, 2024 E2602-24 Revision
Feb. 1, 2022 E2602-22 Revision
April 15, 2009 E2602-09 Revision
May 1, 2015 E2602-09R15 Reaffirmation