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ASTM D7423-23

Current Revision

Standard Test Method for Determination of Oxygenates in C2, C3, C4, and C5 Hydrocarbon Matrices by Gas Chromatography and Flame Ionization Detection

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1.1 This test method covers the gas chromatographic procedure for the quantitative determination of organic oxygenates in C2, C3, C4, and C5 matrices by multidimensional gas chromatography and flame ionization detection. This test method is applicable when the hydrocarbon matrices have a final boiling point not greater than 200 °C. Oxygenate compounds include, but are not limited to, those listed in Table 1. The linear working range for oxygenates is 0.50 mg/kg to 100 mg/kg.

1.2 This test method is intended to determine the mass concentration of each oxygenate in the hydrocarbon matrix. Oxygenate compound identification is determined by reference standards and column elution retention order.

1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

1.4.1 The user is advised to obtain LPG safety training for the safe operation of this test method procedure and related activities. The eLearning training course “Liquefied Petroleum Gases Sampling Safety” is available on the ASTM.org website.

1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.


5.1 The determination of oxygenates is important in the manufacture of ethene, propene, 1-3 butadiene, C4 hydrocarbons, and C5 hydrocarbons. Alcohols, ethers, aldehydes, and ketones are trace impurities in these hydrocarbons. Oxygenates decrease catalyst activity in downstream polymerization processes.

SDO ASTM: ASTM International
Document Number D7423
Publication Date March 1, 2023
Language en - English
Page Count 9
Revision Level 23
Supercedes
Committee D02.D0.04
Publish Date Document Id Type View
March 1, 2023 D7423-23 Revision
June 1, 2017 D7423-17 Revision
Dec. 1, 2016 D7423-16A Revision
Feb. 15, 2016 D7423-16E01 Revision
Feb. 15, 2016 D7423-16 Revision
July 1, 2009 D7423-09 Revision
May 1, 2014 D7423-09R14 Reaffirmation