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ASTM D5799-95(2004)

Historical Reaffirmation

Standard Test Method for Determination of Peroxides in Butadiene

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1.1 This procedure covers the determination of peroxides in butadiene.

1.2 This test method covers the concentrations range of 1 to 10 ppm by mass (ppmw) as available oxygen.

1.3 The values stated in SI units are to be regarded as the standard.

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.


Due to the inherent danger of peroxides in butadiene, specification limits are usually set for their presence. This test method will provide values that can be used to determine the peroxide content of a sample of commercial butadiene.

Butadiene polyperoxide is a very dangerous product of the reaction between butadiene and oxygen that can occur. The peroxide has been reported to be the cause of some violent explosions in vessels that are used to store butadiene.

SDO ASTM: ASTM International
Document Number D5799
Publication Date Nov. 1, 2004
Language en - English
Page Count 3
Revision Level 95(2004)
Supercedes
Committee D02.D0.04
Publish Date Document Id Type View
March 1, 2023 D5799-23 Revision
Dec. 1, 2019 D5799-19 Revision
Jan. 1, 2000 D5799-95 Revision
May 1, 2014 D5799-95R14 Reaffirmation
July 1, 2009 D5799-95R09 Reaffirmation
Nov. 1, 2004 D5799-95R04 Reaffirmation
Nov. 10, 2000 D5799-95R00E01 Reaffirmation