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ASTM D3973-85(2003)

Historical Reaffirmation

Standard Test Method for Low-Molecular Weight Halogenated Hydrocarbons in Water

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1.1 This test method covers the analysis of drinking water. It is also applicable to many environmental and waste waters when adequate validation is included.

1.2 This test method covers the determination of halomethanes, haloethanes, and some related extractable organohalides amenable to gas chromatographic measurement. The applicable concentration range for trihalomethanes is from 1 to 200 g/L. Detection limits depend on the compound, matrix, and on the characteristics of the gas chromatographic system.

1.3 For compounds not specifically included in the precision and bias section the analyst should validate the test method by collecting precision and bias data on actual samples.

1.4 Confirmation of component identities is obtained by observing retention times using gas chromatographic columns of different polarities. When concentrations are sufficiently high (>50 μg/L) confirmation with halogen specific detectors or gas chromatography/mass spectrometry (GC/MS) may be used. Confirmation of purgeable compounds at levels down to 1 μg/L can be obtained using Test Method D 3871 with GC/MS detection.

1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific precautionary statements are given in Section 8.


The incidental conversion of organic material to trihalomethanes and other volatile organohalides during chlorination of water is a possible health hazard and is the object of much research. This test method can be used as a rapid, simple means for determining many volatile organohalides in raw and processed water.

SDO ASTM: ASTM International
Document Number D3973
Publication Date Jan. 10, 2003
Language en - English
Page Count 5
Revision Level 85(2003)
Supercedes
Committee D19.06
Publish Date Document Id Type View
Jan. 1, 1995 D3973-85R95E01 Revision
April 1, 2024 D3973-85R24 Reaffirmation
Dec. 15, 2017 D3973-85R17 Reaffirmation
May 1, 2011 D3973-85R11 Reaffirmation
Jan. 10, 2003 D3973-85R03 Reaffirmation