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ASTM D3749-12

Historical Revision

Standard Test Method for Residual Vinyl Chloride Monomer in Poly(Vinyl Chloride) Resins by Gas Chromatographic Headspace Technique

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1.1 This test method is suitable for determining the residual vinyl chloride monomer (RVCM) content of poly(vinyl chloride) (PVC) homopolymer and copolymer resins for uses other than food contact. The range for this test, based on interlaboratory evaluation, is from 0.1 to 400 ppm RVCM.

1.2 This test method can be adapted to determinations of RVCM in a PVC copolymer resin if the Henry's Law constant at 90°C for that copolymer is known.

1.3 This test method cannot be used for polymer in fused forms, such as cubes or sheets. Refer to Test Method D4443 or Test Method D3680 for these materials.

1.4 This test method is proposed as an alternative to EPA Method 107 for determination of vinyl chloride monomers in dry-resin samples.

1.5 The values stated SI units are to be regarded as the standard.


5.1 Poly(vinyl chloride) resins must contain a minimum possible amount of unreacted, or free, VCM.

5.2 This test method provides a measure of RVCM which is suitable for manufacturing control or specification acceptance purposes.

5.3 Under optimum conditions, a lower level of detection of 2 ppm by volume VCM can be detected in the headspace vapor. Using a 4-g sample, this is equivalent to about 0.02 ppm by mass RVCM in the PVC resin.

SDO ASTM: ASTM International
Document Number D3749
Publication Date Oct. 1, 2012
Language en - English
Page Count 4
Revision Level 12
Supercedes
Committee D20.70
Publish Date Document Id Type View
April 1, 2019 D3749-19 Revision
Nov. 1, 2013 D3749-13 Revision
Oct. 1, 2012 D3749-12 Revision
Dec. 1, 2008 D3749-08 Revision
Jan. 1, 1995 D3749-95 Revision
June 15, 1995 D3749-95R02 Reaffirmation