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ASTM D2360-08

Historical Revision

Standard Test Method for Trace Impurities in Monocyclic Aromatic Hydrocarbons by Gas Chromatography (Withdrawn 2016)

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1.1 This test method covers the determination of the total nonaromatic hydrocarbons, and trace monocyclic aromatic hydrocarbons in the purity of toluene and mixed xylenes by gas chromatography.

1.2 Nonaromatic aliphatic hydrocarbons containing 1 through 10 carbon atoms (methane through decanes) can be detected by this test method at concentrations ranging from 0.001 % to 2.500 weight %.

1.2.1 A small amount of benzene in mixed xylenes may not be distinguished from the nonaromatics and the concentrations are determined as a composite.

1.3 Monocyclic aromatic hydrocarbon impurities containing 6 through 9 carbon atoms (benzene through C9 aromatics) can be detected by this test method at individual concentrations ranging from 0.001 % to 1.000 weight %.

1.4 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E 29.

1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

The determination of hydrocarbon impurities contained in toluene and mixed xylenes used as chemical intermediates and solvents is typically required. This test is suitable for setting specifications and for use as an internal quality control tool where aromatic monocyclic hydrocarbons are produced or are used. This test method is applicable for determining the impurities from the aromatic hydrocarbon production process. Typical impurities are alkanes containing 1 to 10 carbon atoms, benzene, toluene, ethylbenzene (EB), xylenes, and aromatic hydrocarbons containing nine carbon atoms.

Refer to Test Methods D 3797, D 3798, and D 4492 for determining the purity of o-Xylene, p-Xylene, and benzene, respectively.

Refer to Test Method D 6563 for determining the C8 aromatic hydrocarbon distribution in mixed xylenes.

Purity is commonly reported by subtracting the determined expected impurities from 100.00. However, a gas chromatographic analysis cannot determine absolute purity if unknown or undetected components are contained within the material being examined.

SDO ASTM: ASTM International
Document Number D2360
Publication Date Jan. 1, 2008
Language en - English
Page Count 5
Revision Level 08
Supercedes
Committee D16.01
Publish Date Document Id Type View
June 1, 2011 D2360-11 Revision
Jan. 1, 2008 D2360-08 Revision
June 1, 2007 D2360-07 Revision
Aug. 1, 2004 D2360-04A Revision
Jan. 1, 2004 D2360-04E01 Revision
Jan. 1, 2004 D2360-04 Revision
June 10, 2003 D2360-03 Revision
June 10, 2000 D2360-00 Revision