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ASTM D1319-03

Historical Revision

Standard Test Method for Hydrocarbon Types in Liquid Petroleum Products by Fluorescent Indicator Adsorption

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1.1 This test method covers the determination of hydrocarbon types over the concentration ranges from 5 to 99 volume % aromatics, 0.3 to 55 volume % olefins, and 1 to 95 volume % saturates in petroleum fractions that distill below 315°C. This test method may apply to concentrations outside these ranges, but the precision has not been determined. Samples containing dark-colored components that interfere in reading the chromatographic bands cannot be analyzed.

1.2 This test method is intended for use with full boiling range products. Cooperative data have established that the precision statement does not apply to narrow boiling petroleum fractions near the 315°C limit. Such samples are not eluted properly, and results are erratic.

1.3 The applicability of this test method to products derived from fossil fuels other than petroleum, such as coal, shale, or tar sands, has not been determined, and the precision statement may or may not apply to such products.

1.4 This test method has two precision statements depicted in tables. The first table is applicable to unleaded fuels that do not contain oxygenated blending components. It may or may not apply to automotive gasolines containing lead antiknock mixtures. The second table is applicable to oxygenate blended (for example, MTBE, ethanol) automotive spark ignition fuel samples with a concentration range of 13-40 volume percent aromatics, 4-33 volume percent olefins, and 45-68 volume percent saturates.

1.5 The oxygenated blending components, methanol, ethanol, methyl-tert-butylether (MTBE), tert-amylmethylether (TAME), and ethyl-tert-butylether (ETBE), do not interfere with the determination of hydrocarbon types at concentrations normally found in commercial blends. These oxygenated components are not detected since they elute with the alcohol desorbent. Other oxygenated compounds shall be individually verified. When samples containing oxygenated blending components are analyzed, correct the results to a total-sample basis.

1.6 The values stated in SI units are to be regarded as standard.

Note 1—For the determination of olefins below 0.3 volume %, other test methods are available, such as Test Method D 2710.

1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 7, 8.1, and 10.5.


SDO ASTM: ASTM International
Document Number D1319
Publication Date Nov. 1, 2003
Language en - English
Page Count 8
Revision Level 03
Supercedes
Committee D02.04.0C
Publish Date Document Id Type View
Aug. 1, 2020 D1319-20A Revision
July 15, 2020 D1319-20 Revision
Aug. 1, 2019 D1319-19 Revision
Oct. 1, 2018 D1319-18 Revision
Dec. 1, 2015 D1319-15 Revision
Oct. 1, 2014 D1319-14 Revision
May 1, 2013 D1319-13 Revision
May 1, 2010 D1319-10 Revision
Oct. 15, 2008 D1319-08 Revision
Nov. 1, 2003 D1319-03E01 Revision
Nov. 1, 2003 D1319-03 Revision
April 10, 2002 D1319-02A Revision
Jan. 10, 2002 D1319-99 Revision
Jan. 10, 2002 D1319-02 Revision
Not Available D1319-95A Revision
Not Available D1319-89 Revision